[1,2-Bis(diphenylphosphino)ethane-κ2 P,P′](2-carboxylatothiophenolato-κ2 O,S)nickel(II) methanol solvate
نویسندگان
چکیده
In the title complex, [Ni(C(7)H(4)O(2)S)(C(26)H(24)P(2))]·CH(3)OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio-salicylate ligand and the two P atoms of the chelating Ph(2)PCH(2)CH(2)PPh(2) ligand. There is hydrogen bonding between the methanol solvent mol-ecule and the carbonyl O atom of the thio-salicylate ligand.
منابع مشابه
[μ-1,2-Bis(diphenylphosphino)ethane-κ2 P:P′]bis{[1,2-bis(diphenylphosphino)ethane-κ2 P,P′]cyanidocopper(I)} methanol disolvate
The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis-(diphenyl-phosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent mol-ecules. The angles around the central metal atom indicate that each Cu(I) atom is located in the center of a distorted tetra-hedron. The coordination sphere of ea...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009